Reaction Schemes That Are Easily Confused with a Reversible First-Order Reaction
نویسندگان
چکیده
منابع مشابه
On the ambiguity of the reaction rate constants in multivariate curve resolution for reversible first-order reaction systems.
If for a chemical reaction with a known reaction mechanism the concentration profiles are accessible only for certain species, e.g. only for the main product, then often the reaction rate constants cannot uniquely be determined from the concentration data. This is a well-known fact which includes the so-called slow-fast ambiguity. This work combines the question of unique or non-unique reaction...
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ژورنال
عنوان ژورنال: International Journal of Chemical Kinetics
سال: 2015
ISSN: 0538-8066
DOI: 10.1002/kin.20960